Nucleophilic Chemistry of the Synthesized Magnesium Oxide (Magnesia) Nanoparticles via [email protected] Process for Removal of Sulfurous Pollutant
Document Type : Research Paper
Abstract
In this scientific research, magnesium oxide (MgO) nanoparticles were synthesized from magnesium nitrate and ammonium solutions via [email protected] process. The structure and the morphology of the synthesized nanoparticles has been identified and characterized by X-ray diffraction (XRD), N2-BET (Brunauer-Emmett-Tell), scanning electron microscopy (SEM) and fourier transform infrared (FTIR) techniques. The crystallite size of nano MgO was in the range of (100 nm (and surface area of 596.39 m2/g. The (2-chloro ethyl phenyl sulfide) 2-CEPS are a sulfurous pollutant. This compound can cause the contaminations of environment. In this survey, we used MgO nanoparticles for removal of 2-CEPS molecule. The results of UV/Vis irradiation for the weight ratio of 1:40 (2-CEPS: MgO nanoparticles) at ambient temperature emphasized that 2-CEPS molecule has the highest amount of removal about 61% and 70% by nanoparticles in the isopropanol and n-heptane solvents after 8 hours, respectively. Although, for the weight ratios of 1:10, 1:20 and 1:30 very lower degradation of the sulfurous pollutant (from the same conditions) was observed. Elimination single product; i.e. phenyl vinyl sulfide (PVS) has been identified via GC-MS analysis.
(2012). Nucleophilic Chemistry of the Synthesized Magnesium Oxide (Magnesia) Nanoparticles via [email protected] Process for Removal of Sulfurous Pollutant. International Journal of Bio-Inorganic Hybrid Nanomaterials, 1(3), 175-182.
MLA
. "Nucleophilic Chemistry of the Synthesized Magnesium Oxide (Magnesia) Nanoparticles via [email protected] Process for Removal of Sulfurous Pollutant". International Journal of Bio-Inorganic Hybrid Nanomaterials, 1, 3, 2012, 175-182.
HARVARD
(2012). 'Nucleophilic Chemistry of the Synthesized Magnesium Oxide (Magnesia) Nanoparticles via [email protected] Process for Removal of Sulfurous Pollutant', International Journal of Bio-Inorganic Hybrid Nanomaterials, 1(3), pp. 175-182.
VANCOUVER
Nucleophilic Chemistry of the Synthesized Magnesium Oxide (Magnesia) Nanoparticles via [email protected] Process for Removal of Sulfurous Pollutant. International Journal of Bio-Inorganic Hybrid Nanomaterials, 2012; 1(3): 175-182.